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Synthesis and Characterization of Tin and Germanium Based Semiconductor Nanocrystals

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posted on 2021-11-14, 23:59 authored by Xu, Ying

Inorganic nanomaterials are being actively researched due to their unique physical and chemical properties. These materials can be used for a wide variety of applications and technologies which have stimulated research into the discovery, understanding and control of the morphology of materials at the nanoscale. Biologists have recently integrated biomaterials with semiconductor nanoparticles to expand their applications to include biosensing, bioimaging and therapeutic strategies. Since the water solubility of semiconductor nanoparticles is crucial for bioapplications, the fabrication of water-soluble semiconductor nanocrystals with tailored properties has become more significant.  This thesis is focused on the solution phase synthesis of nanoparticles and nanowires containing the element tin. This includes tin nanoparticles, tingermanium alloy nanowires, tin sulphide nanoparticles and tin telluride nanoparticles. The aim of this research was to synthesize nanocrystals with tightly controlled size and shape for various applications,in particular for bioapplications. The properties, potential applications and crystal structure of target materials have been discussed in Chapter 1.  The target materials synthesized by using chemical reaction in the presence of surfactant were characterized primarily by Transmission Electron Microscopy (TEM), Energy Dispersive X-ray Spectroscopy (EDX) and Selected Area Electron Diffraction (SAED). Powder X-ray Diffraction (XRD), Scanning Transmission Electron Microscopy (STEM), Scanning Electron Microscopy (SEM), Ultraviolet-Visible Microscopy Absorption (UV-VIS), Fourier Transform Infrared (FTIR), Photoluminescence (PL) and Diffuse Reflectance were also used extensively (Chapter 2).  The third chapter of this thesis focuses on the the development of a facile and cheap route for the synthesis of tin nanoparticles by reducing a tin precursor in an organic solvent. The low-melting tin nanoparticles have been considered as a good catalyst for the growth of semiconductor nanowires.  The fourth chapter in this thesis focuses on the development of a convenient synthesis of tin germanium alloy nanowires via solution-liquid-solid growth (SLS). Tin germanium alloy nanowires were synthesized through a self-catalyzed process in which the wires were grown from in situ made Sn droplets and Ge(Ph)₃Cl. The factors affecting morphology were ascertained and the growth direction, composition, local crystal structure and possible growth mechanism have been investigated.  The fifth chapter in this thesis focuses on the development of a novel one-pot synthesis of water-soluble SnS nanoparticles. The synthesis of SnS nanoparticles involves the reaction of inorganic starting materials SnBr₂ and Na₂S in the presence of various ethanolamine derivatives in ethylene glycol. Optical studies of as synthesized SnS nanoparticle show size dependent effects in both absorbance and reflectivity.  The sixth chapter in this thesis focuses on the development of a facile direct synthesis of water dispersible SnTe nanoparticles. The optical properties of prepared SnTe nanoparticles were determined.  The final chapter in this thesis summarizes the main findings of this study and draws out recommendations for future work. In this study, some novel contributions have been made to produce facile one-pot synthesis of tin germanium nanowires and water soluble, size controlled tin chalcogenides nanoparticles. The main future work for tin germanium alloy naowires is to develop the method to produce nanowires without seed nanoparticles for optoelectronics applications. Further work is also needed to optimize the water synthesis of SnTe nanoparticles.


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Date of Award



Te Herenga Waka—Victoria University of Wellington

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Author Retains Copyright

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Degree Grantor

Te Herenga Waka—Victoria University of Wellington

Degree Level


Degree Name

Doctor of Philosophy

Victoria University of Wellington Item Type

Awarded Doctoral Thesis



Victoria University of Wellington School

School of Chemical and Physical Sciences


Tilley, Richard; Al-Salim, Najeh