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Structural Studies of Some Sulphur Bonding Ligands

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thesis
posted on 05.11.2021, 02:47 by Burns, Gary Robert

This thesis is a study of the structures and energetics of the metal complexes of dithizone, C6H5.N:N.C(S).NH.NH.C6H5, and thiocarbohydrazide, H2N.HN.C(S).NH.NH2. Dithizone was first prepared and studied by E. Fisher as part of his classic work on phenylhydrazine. It is a weak acid capable of forming intensely coloured metal complexes with at least twenty three elements and, since the work of Walter and H. Fischer, has been used extensively for trace metal analysis, particularly in solvent extraction procedures. The applications of dithizone in analytical chemistry have been covered in numerous review articles and have also been the subject of a book.

History

Copyright Date

01/01/1966

Date of Award

01/01/1966

Publisher

Te Herenga Waka—Victoria University of Wellington

Rights License

Author Retains Copyright

Degree Discipline

Chemistry

Degree Grantor

Te Herenga Waka—Victoria University of Wellington

Degree Level

Doctoral

Degree Name

Doctor of Philosophy

Victoria University of Wellington Item Type

Awarded Doctoral Thesis

Language

en_NZ

Victoria University of Wellington School

School of Chemical and Physical Sciences

Advisors

Duncan, J F