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Download fileStructural Studies of Some Sulphur Bonding Ligands
thesis
posted on 2021-11-05, 02:47 authored by Burns, Gary RobertThis thesis is a study of the structures and energetics of the metal complexes of dithizone, C6H5.N:N.C(S).NH.NH.C6H5, and thiocarbohydrazide, H2N.HN.C(S).NH.NH2. Dithizone was first prepared and studied by E. Fisher as part of his classic work on phenylhydrazine. It is a weak acid capable of forming intensely coloured metal complexes with at least twenty three elements and, since the work of Walter and H. Fischer, has been used extensively for trace metal analysis, particularly in solvent extraction procedures. The applications of dithizone in analytical chemistry have been covered in numerous review articles and have also been the subject of a book.
History
Copyright Date
1966-01-01Date of Award
1966-01-01Publisher
Te Herenga Waka—Victoria University of WellingtonRights License
Author Retains CopyrightDegree Discipline
ChemistryDegree Grantor
Te Herenga Waka—Victoria University of WellingtonDegree Level
DoctoralDegree Name
Doctor of PhilosophyVictoria University of Wellington Item Type
Awarded Doctoral ThesisLanguage
en_NZVictoria University of Wellington School
School of Chemical and Physical SciencesAdvisors
Duncan, J FUsage metrics
Keywords
LigandsCoordination compoundsThiocarbohydrazideDithizoneSchool: School of Chemical and Physical Sciences039999 Chemical Sciences not elsewhere classifiedMarsden: 250200 Inorganic ChemistryDegree Discipline: ChemistryDegree Level: DoctoralDegree Name: Doctor of PhilosophyChemical Sciences not elsewhere classified