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An Investigation of Some Reactions of N-Chlorocompounds

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thesis
posted on 05.11.2021, 02:46 by Millar, Keith Raymond

A vast volume of literature exists on this subject, the major portion being concerned with nucleophilic aliphatic substitution reactions covered by the general equation:- Y + Alk - X --> Alk - Y + X (SN) where the new bond is formed by co-ordination, and the old one broken by heterolysis, as indicated by the dotted line. There is necessarily and electron transfer from the substituting species Y to the centre of substitution in Alk, and from this centre to the expelled group X; hence Y becomes formally one electronic unit more positive and X one unit more negative.

History

Copyright Date

01/01/1963

Date of Award

01/01/1963

Publisher

Te Herenga Waka—Victoria University of Wellington

Rights License

Author Retains Copyright

Degree Discipline

Chemistry

Degree Grantor

Te Herenga Waka—Victoria University of Wellington

Degree Level

Doctoral

Degree Name

Doctor of Philosophy

Victoria University of Wellington Item Type

Awarded Doctoral Thesis

Language

en_NZ

Victoria University of Wellington School

School of Chemical and Physical Sciences

Advisors

England, B D