Belite cement was prepared using nano-silicas extracted from three different agricultural wastes–black rice husk ash (BRHA), bagasse ash (BA), and palm oil fuel ash (POFA)–which were reacted at 1200 − 1400 °C with CaC2 residue as calcium source. The product was compared with that from CaCO3. Nano-silica extracted from BRHA was of very fine particle size (surface area 312.4 m2/g and V/S ratio 0.35 × 106 cm) and being highly reactive, forms β-C2S at lower firing temperatures; however, at higher temperatures, less-desirable γ-polymorphs are formed. Nano-silica extracted from POFA contains Na2O, Al2O3, and K2O impurities, which stabilize the β and α-forms and delay the transformation to γ-phase. This is reflected in relatively high compressive strength at firing temperature above 1200 °C, compared to other mixtures. Thus, these results indicate that the best combination of these waste materials for the preparation of belite cement phases is POFA ash and CaC2 residue.
History
Preferred citation
Kunchariyakun, K., Sinyoung, S., Asavapisit, S. & MacKenzie, K. J. D. (2022). Comparative study on the preparation of belite cement from nano-silicas extracted from different agricultural wastes with calcium carbide residue. Journal of Sustainable Cement-Based Materials, 1-12. https://doi.org/10.1080/21650373.2021.2025164